Phase composition and
geochemistry of carbonatites from Tromsø area, Norway.
N.S. Gorbachev*,
E. Ravna** , A.N. Nekrasov*., K. Kullerud**
*Institute
of experimental mineralogy RAS, Chernogolovka
Russia
* Tromsø, University,
Tromsø, Norway
gor@iem.ac.ru
For explore of
genesis of mantle carbonate magmas have been studied the phase relations
and geochemistry of garnet-bearing ultra-high pressure carbonatites (UHPC)
Tromsø area, Norway. The matrix of UHPC is represented by carbonate C
calcite-dolomite composition with inclusions of garnet Grt and accessory
minerals - apatite, sphene, ilmenite, rutile. The samples were studied
by by PC-controlled
scanning electron microscope Tescan VEGA TS
5130MM with detector of secondary and backscattered electron on
the YAG-crystals and energy dispersive X-ray microanalyzer with
semi-conductor Si(Li) detector INCA Energy 350.microprobe,
trace elements were determined by ICP MS.
On structure and
composition it is allocated
three
generation of Grt: early, Grt1, of pyr15-gros25-alm60 composition,
depleted in REE (<2.10-2 wt.%); reacting Grt2-3 of
pyr5-gros65-alm30 composition, anomalously enriched (up to 4-8 wt.%) in
LREE .
The abundances
of trace elements in the UHPC, its carbonate C and silicate Si fraction
were examination. Compared to silicate, carbonate fraction is enriched
in Ba, Rb, Nb, Sr, P, Zr, depleted in Hf, Ti, Th, Ta. Carbonate and
silicate fraction of UHPC differ in REE concentrations and the character
of its dependence from atomic number N REE. Silicate fraction enriched
in REE, the dependence of the normalized for chondrite REE
concentrations CN from N REE has negative slope with slight
Eu minimum. In the carbonate fraction to the dependence of CN-N
REE has an extreme character with maximum at Gd-Tb. The largest
differences are observed in the distribution of LREE. In the silicate
fraction CN REE reduced from 500 at La to 50 for Sm, in
carbonate fraction CN REE rise from 30 to 45 at La to Sm.
Starting from Gd to Lu REE behavior is similar in silicate fraction CN
REE reduced to 8, and in carbonate C fraction up to 5 (fig. 1).
Fig. 1. Normalize for
chondrite concentration of trace elements in UHPC, its carbonate C and
silicate Si fractions
Since the
silicate fraction to UHPC dominates Grt, then we can assume that D REE -
partition coefficients between silicate and carbonate fraction to
characterize the partition coefficients REE between Grt and carbonatite
melt C.
Fig.
3.
Partition
coefficients REE between silicate and carbonate fraction of UHPC
(D REE Si/C)
and partition
coefficients REE between Grt and carbonatite melt (D
REE Grt/Cm)
(for our
experimental datas).
However, D REE
Si/C~D REE Grt/C in the UHPC differ from the experimental D Grt/C. In
UHPC dependence of D REE Si/C is an extreme character, decreasing from
18 to 1.2 for La to Gd-Tb, and then increasing to 2 at Tm-Lu. According
to our experimental data, the dependence of D REE Grt / C is positive,
increasing from 0.07 at La to 10 at Lu (fig. 3).
Anomalous REE
distribution in UHPC indicates a lack of equilibrium between Grt and
carbonatite melt at formation of carbonatite melt at melting of uper
mantle.
This study was financially supported by RFBR grant
09-05-0113-a,
12-05-00777-a.- |