Temperature evolution of
early Proterozoic ultrabasite intrusion of the Belomorsky region
(Karelia)
Akimenko M.I., Asavin A.M.
GEOHI RAS
Development of large Cu-Ni
deposits of the Kola peninsula (Monchetundra) causes significant
interest in the Early Proterozoic intrusions of basic and ultrabasic
composition, which are known as “Belomorsky druzite complex”, for the
first time described more than of a century ago. We have investigated
one of the manifestations of ultrabasite discovered by the geophysic and
confirmed before field geological studies.
As a result a
petrographical study it is established that ultrabasite are
orthopyroxene -clinopyroxene of species. Chemical analysis and
conversion on CIPW(Table 1).
Additional
interest is dispersed
sulfide impregnations
in the sample (Fig. 1).
Perhaps
further work will clarify the
composition and the
paragenesis of
these
sulfides.
Table
1. The chemical composition
of the ultrabasic sample
and recalculate on the CIPW
norm
Oxides Wt% |
SiO2 |
Al2O3 |
TiO2 |
Fe2O3 |
MnO |
K2O |
CaO |
MgO |
Na2O |
P2O5 |
сумма |
|
|
50.17 |
6.23 |
0.53 |
14.62 |
0.251 |
0.37 |
8.75 |
16.81 |
1.48 |
0.073 |
|
|
|
Element ppm |
Cr |
S |
V |
Co |
Ni |
Cu |
Zn |
Rb |
Sr |
Y |
Zr |
Nb |
Ba |
2451 |
290 |
145 |
118 |
943 |
35 |
91 |
12 |
88 |
10 |
28 |
3 |
180 |
CIPW
(Wt%) |
an |
or |
ab |
an |
di |
hy |
ol |
mt |
il |
ap |
|
|
|
42.51 |
2.23 |
12.77 |
9.450 |
27.72 |
31.09 |
12.52 |
3 |
1.026 |
0.17 |
|
|
|
Primary
large
(modify) orthopyroxene
crystals occur
in the rock. It forms
large grains or
porphyroblasts with
the decay structures,
often with ingrowths of other
minerals – olivine,
clinopyroxene (Fig.
2). The composition of
orthopyroxene is quite
ferruginous enstatite
up to 75% and 24%
ferrosilite.
Apparently,
these inclusions are the
products of the reaction
changes the primary
intrusive harzburgite
and conversion them into
orthopyroxene lherzolites.
Olivine in thin section
is represented by two
generations of large
porphyritic crystals
and fine aggregate
intergrowths with clinopyroxene (Fig 3-4).
|
|
Fig.
1.
Sulfides.
Polished section. |
Fig.
2.
The inclusion of
fine-grained olivine
aggregate in a
primary porphyry
crystal orthopyroxene
(Nicoli +) |
|
|
Fig.3.
Idiomorphic crystals
of the newly formed
clinopyroxene (Nicoli
+) |
Fig.4.
The inclusion of
fine-grained olivine
aggregate in the
crystal orthopyroxene
(Nicoli +) |
For a given
species rock is characterized
by the absence of
serpentinization of olivine, which
indicates high-T sub-magmatic
processes after
conversion. Such processes
could be associated
with a common regional stage
of high-temperature metamorphism
(Early Proterozoic ?), or with
intra-chamber postmagmatic
processes –
pyroxenezatiton, amphibolization.
The low
degree of weathering
of rock raises the problem of
estimating the age of these
manifestations. If we
consider them as part of
the Proterozoic igneous
complexes, then they should have
by now be strongly
serpentinized. Absence of
serpentinization can be
attributed to either
the younger age of the
intrusions, or younger age
post-magmatic processes
and metamorphism. In any
case, the development of
small area of that type of
rocks this in the
evidence of either their
affinity to the apical
or the root of the
plutonic bodies.
Clinopyroxene
in the rock in the main
forms euhedral
small crystals, in contrast to
orthopyroxene in it
is not observed decay
structures (Fig. 3)
Individual clinopyroxene
crystals are larger and
with more rough borders,
probably formed at the
magmatic stage. Sulphides
form rims around
orthopyroxene crystals
and single grain (Fig.
1). The chemical composition
of minerals is
presented in Table 2.
Table 2.
The chemical composition of
minerals.
|
orthopyroxene |
Clinopyroxene |
Olivine |
Magnetite |
Minal
% |
SiO2 |
|
54.08 |
53.82 |
|
52.83 |
53.17 |
|
37.19 |
0.06 |
0.03 |
Mt |
57 |
50.4 |
FeO |
|
15.63 |
15.86 |
|
4.31 |
4.26 |
|
26.93 |
60.64 |
56.28 |
Ch |
18.5 |
21.6 |
CaO |
|
0.44 |
0.24 |
|
24.28 |
24.54 |
|
0.01 |
|
|
Sp |
5 |
8.1 |
MgO |
|
27.68 |
27.24 |
|
16.5 |
16.48 |
|
34.87 |
0.92 |
1.25 |
Her |
4.6 |
5 |
Al2O3 |
|
0.87 |
0.77 |
|
0.53 |
0.55 |
|
|
8.29 |
10.25 |
Ulsp |
12.1 |
12.9 |
TiO2 |
|
|
|
|
|
|
|
|
3.7 |
3.92 |
Т,С |
328 |
308 |
Cr2O3 |
|
|
|
|
|
|
|
|
21.51 |
24.86 |
|
|
|
MnO |
|
|
|
|
|
|
|
|
0.39 |
0.42 |
|
|
|
CoO |
|
|
|
|
|
|
|
|
0.13 |
0.09 |
|
|
|
Summa |
|
98.78 |
98 |
|
98.5 |
99.07 |
|
99.41 |
96.42 |
98.09 |
|
|
|
Мineral
Component (%) |
En |
74 |
75 |
Di |
96.1 |
96.1 |
Fo |
70 |
|
|
|
|
|
|
Fs |
24 |
24 |
Нe |
5.3 |
5.3 |
Fa |
30 |
|
|
|
|
|
Spinel
group minerals
contain
50%
magnetite
component
and
about
20% of
chromite
component,
you can also
note
the high
titanium content
(up
to
12.9%
ulvoshpinel component).
The calculation
of
spinel-olivine
equilibrium
shows
[Fabri
1975]
a temperature of about
300C.
Calculation
of
bipyroxene
thermometer
[Perchuk,
1976],
the formation temperature of
clinopyroxene
was
800.
The history
of the
rock, so
apparently
included
several stages.
The primary
magma
-
olivine-orthopyroxene
(formed
from the
large
rock
structure
panidiomorf).
Secondary
magmatic
(?
Metasomatic)
phase of
800-900 ° C
-
pyroxenezatiton:
Clinopyroxene
-olivine-orthopyroxene
equilibrium.
Metasomatic
transformation -
metamorphism of
300-400 °
C -
clinopyroxene-olivine-spinel.
Reference
1.
Perchuk
LL,
Ryabchikov ID
(1976)
Phase
correspondence in
mineral systems
//
Cyrillic.
M. "Nedra",
1976,
287
pp.
2.
Fabri Cs J (1979) Spinel-olivine geothermometry in peridotites
from ultramafic complexes // Contrib Mineral Petrol 69:329-336 |