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Platinum-group minerals (PGMs) of the Bor-Uryakh massif (Maimecha-Kotui Province)

Malitch K.N.*, Badanina I.Yu.*, Goncharov M.M.**, Lopatin G.G.**

* A.P. Karpinsky Russian Geological Research Institute (VSEGEI), St. Petersburg, Russia; ** Polar Geological Prospecting Venture, Khatanga, Russia

dunite@yandex.ru

 

Introduction. The Bor-Uryakh massif of ultramafic and alkaline rocks, like other similar complexes (e.g. Guli, Kugda and Odikhincha), is situated in the limits of the Maimecha-Kotui Province, northern part of the Siberian Craton (Egorov, 1991; Kogarko et al., 1995; Malitch, 1999, among others). In this contribution, we focus on morphology and mineral chemistry of PGM nuggets closely linked to the Bor-Uryakh massif, which is considered a promising PGE target within the Maimecha-Kotui Province.

Geology and sample location. The Bor-Uryakh massif, discovered by Yu.M. Sheinmann in 1944, occupies an area of 18.5 km2 (Fig. 1) and intrudes Late Proterozoic (Middle Riphean) and Cambrian terrigenous-carbonaceous rocks, forming a dome-like structure. Core-zone olivinite (metadunite?) comprising olivine and titanomagnetite grades into dunite with nodular chromitite in the outer part of the massif. The core-zone olivinite has been intruded by vein-like course grained ore-rich olivinite (up to 20-50% of titanomagnetite and perovskite), alkaline syenite and rarely by melteigeite and calcite carbonatite. Based on K-Ar dating the age of phlogopite from veins ranges from 215 to 225 Ma (Egorov, 1991).

The central part of the Bor-Uryakh massif represents an erosion crater, which is rimmed by a circular mountain ridge composed of Cambrian and Riphean rocks. The main physiographic structure in the area is the Buor-Uryakh  river valley, which originates at the confluence of two streams in the central part of the massif (Fig. 1) and flows north-eastwards through the circular mountain ridge. According to exploration forecasts given by Polar Geological Prospecting Venture, the Quaternary sediments in the Bor-Uryakh area are promising for PGE-mineralization, with grades up to 0.265 PGE g/m3. This study is based on 19 Os-Ir and Pt-Fe nuggets (size range between 0.1 and 0.25 mm), which were sampled from Quaternary and recent sediments (exploration lines L-130, L-120, L-98) in the northeastern part the massif (Fig. 1).

 

 

Fig. 1. Schematic geological map of the Bor-Uryakh massif (after Vasilev & Zolotukhin, 1975 and Egorov, 1991).

 

Analytical techniques. Initially, morphology of PGM grains, represented by individual crystals and polymineral aggregates, was documented by scanning electron microscopy (SEM). The grains were, then, mounted and polished, described and analyzed by electron microprobe analysis (EMPA) (Camscan-4 with energy-dispersive spectrometer Link-10 000 and wavelength spectrometer Microspec, JSC Mekhanobr-Analyt, St.-Petersburg, Russia and ARL-SEMQ microprobe with four wavelength-dispersive spectrometers and equipped with a LINK energy dispersive analyser, Institute of Geological Sciences, University of Leoben, Austria).

Results and discussion. The majority of PGM nuggets at Bor-Uryakh, both single crystals (e.g., subhedral, euhedral) and aggregates of euhedral crystals, are Os-rich alloys that prevail over Pt-Fe alloys. Typical characteristic textures of Pt-Fe and Os-Ir alloys and minute intergrowths of PGMs are illustrated in Fig. 2. According to the classification by Cabri & Feather (1975) and Harris & Cabri (1991), PGM nuggets at Bor-Uryakh are osmium (with considerable inter-nugget variation of Ir and Ru) and possibly ferroan platinum. To avoid confusion with osmium as element, we refer to the Os-rich alloy grains as osmium (Os content > 80 %) and iridian osmium (Os, Ir).

Majority of the Os-rich nuggets at Bor-Uryakh are iridian osmium, with minor amounts of chengdeite Ir3Fe. Os-rich minerals also occur as inclusions and lamellae in Pt-Fe alloy grains (Fig. 2c, d), which have a composition close to Pt2Fe. Mineral with composition Pt2Fe is not known in the synthetic system Pt Fe (Massalski, 1993), although there are many naturally occurring Pt-Fe alloys with a composition close to Pt2Fe (Cabri et al., 1996; Weiser & Bachmann, 1999; Sluzhenikin, 2000; Malitch & Thalhammer, 2002; unpublished data).

Equilibrium phase relationships of Os-rich alloys at Bor-Uryakh, based on the binary system Os-Ir (Massalski, 1993), and the presence of inclusions and lamellae of Os-rich alloys in Pt-Fe alloy are indicative of high-temperature origin of PGMs. Therefore, the derivation of the studied PGM nuggets from rocks of the Bor-Uryakh massif is obvious. We further propose that Os-rich and Pt-Fe alloys might have been derived from distinct sources (e.g., chromitite and dunite, respectively). This study suggests that PGMs from Bor-Uryakh share similar features with those from the Guli and some other zoned-type ultramafic complexes (also known as Aldan-, Uralian- and Alaskan-type massifs).     

 

 

Fig. 2. Back-scattered electron images of Os-rich and Pt-Fe alloy nuggets from the Bor-Uryakh massif. Os osmium, (Os, Ir) iridian osmium, Pt2Fe ferroan platinum.

Acknowledgements. The study was supported by Russian Foundation for Basic Research (grant 09-05-01242-a) and  Ministry of Education and Science of Russian Federation (State Contract 02.740.11.0726).

 

References:

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Cabri L.J., Harris D.C., Weiser T.W. Mineralogy and distribution of platinum-group minerals (PGM) placer deposits of the world // Exploration and Mining Geology. 1996. Vol. 5. P. 73-167.

Egorov L.S. Ijolite-carbonatite plutonism (the Maimecha-Kotui Complex of Polar Siberia as an example). Leningrad: Nedra Press, 1991. 260 pp. (in Russian).

Harris D.C., Cabri L.J. Nomenclature of platinum-group-element alloys: review and revision // Canadian Mineralogist. 1991. Vol. 29. P. 231-237

Kogarko L.N., Kononova V.A., Orlova M.P., Wooley A.R. Alkaline rocks and carbonatites of the world. Part 2: Former USSR. London, UK: Chapman  and Hall, 1995. 226 p.

Malitch K.N. Platinum-group elements in clinopyroxenite-dunite massifs of the Eastern Siberia (geochemistry, mineralogy, and genesis). St.-Petersburg: Saint Petersburg Cartographic Factory VSEGEI Press, 1999. 296 p (in Russian).

Malitch K.N., Thalhammer O.A.R. Pt-Fe nuggets derived from clinopyroxenite-dunite massifs, Russia: a structural, compositional and osmium-isotope study // Canadian Mineralogist. 2002. Vol. 40. P. 395-418.

Massalski T.B. (ed) Binary alloy phase diagrams. Amer. Soc. Metals, Metals Park, Ohio, 1993. 2224 p.

Sluzhenikin S.F. Low sulphide platinum ores in differentiated basic-ultrabasic inrusions of the Norilsk region. Ph.D. thesis, Moscow: IGEM RAS, 2000. 26 p (in Russian).

Weiser T., Bachmann H.-G. Platinum-group minerals from the Aikora River area, Papua New Guinea // Canadian Mineralogist. 1999. Vol. 37. P. 1131-1145.

Vasilev Yu.R., Zolotukhin V.V. Petrology of the ultramafites in the North of the Siberian Platform and some problems of their genesis. Novosibirsk: Nauka Press, 1975. 271 p (in Russian).